91928

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91928

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2′,4′,6′-Trihydroxyacetophenone monohydrate

puriss. p.a., matrix substance for MALDI-MS, ≥99.5% (HPLC)

Synonym:2-Acetylphloroglucinol, THAP
CAS Number:480-66-0
Linear Formula:(HO)3C6H2COCH3·H2O
Molecular Weight:186.16
Beilstein Registry Number:1911197
EC Number:207-556-5
MDL number:MFCD00149091
PubChem Substance ID:24889584

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Description

ApplicationUsed in MALDI analysis of acidic glycans and glyco­peptides in negative ion mode. Lower limit of detection than 6-aza-2-thiothimidine.1

Properties

gradematrix substance for MALDI-MS
 puriss. p.a.
assay≥99.5% (HPLC)
color light yellow
mp218-222 °C
 219-221 °C(lit.)
cation tracesCa: ≤200 mg/kg
 Cd: ≤5 mg/kg
 Co: ≤5 mg/kg
 Cr: ≤5 mg/kg
 Cu: ≤5 mg/kg
 Fe: ≤5 mg/kg
 K: ≤50 mg/kg
 Mg: ≤5 mg/kg
 Mn: ≤5 mg/kg
 Na: ≤50 mg/kg
 Ni: ≤5 mg/kg
 Pb: ≤5 mg/kg
 Zn: ≤5 mg/kg
suitabilityin accordance for UV test

Safety

Personal Protective Equipmentdust mask type N95 (US), Eyeshields, Gloves
Hazard CodesXi
Risk Statements36/37/38
Safety Statements26-36
WGK Germany3

References

Cited Reference1. Papac, D.I., et al., , Analysis of acidic oligosaccharides and glycopeptides by matrix-assisted laser desorption/ ionization time-of-flight mass spectrometry. Anal. Chem. 68, 3215-23, (1996) Abstract
BeilsteinBeil. 8,IV,2729
referenceAldrich MSDS 1, 1774:C / Corp MSDS 1 (2), 3463:B / FT-IR 1 (2), 43:A / FT-IR 2 (2), 2424:B / FT-NMR 1 (2), 860:C / IR-Spectra (3), 872:F / IR-Spectra (2), 763:D / NMR-Reference 2 (2), 43:C / RegBook 1 (2), 1649:M / Structure Index 1, 260:D:3